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The correct statement regarding the comparison of staggered and eclipsed conformations of ethane, is:

(A)

The staggered conformation of ethane is more stable than eclipsed conformation, because staggered conformation has no torsional strain.

(B)

The staggered conformation of ethane is less stable than eclipsed conformation, because staggered conformation has torsional strain.

(C)

The eclipsed conformation of ethane is more stable than staggered conformation, because eclipsed conformation has no torsional strain.

(D)

The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has torsional strain.

NEET - Medical UG-2016 Medium

Answer & Solution:

The staggered conformation of ethane is more stable than eclipsed conformation, because staggered conformation has no torsional strain.

Consider both the conformations of ethane.

First figure is staggered and the second one is Eclipsed conformation of ethane. In staggered condition the torsional strain is very low comparing to the eclipsed where it is very high.

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Q1:

The correct structure of the product A formed in the reaction:

is :

(A)

(B)

(C)

(D)

NEET - Medical UG-2016 Medium

Q2:

Which among the give nmolecules can exhibit tautomerism?

(A)

Both II and III

(B)

III only

(C)

Both I and III

(D)

Both I and II

NEET - Medical UG-2016 Hard

Q3:

2,3–Dimethyl–2–butene can be prepared by heating which of the following compounds with a strong acid ?

(A)

\(\large \left ( CH_{3} \right )_{2}C=CH-CH_{2}-CH_{3}\)

(B)

\(\large \left ( CH_{3} \right )_{2}CH-CH_{2}-CH=CH_{2}\)

(C)

(D)

\(\large \left ( CH_{3} \right )_{3}C-CH=CH_{2}\)

NEET - Medical UG-2015 Medium

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